AMBIENTUM BIOETHICA BIOLOGIA CHEMIA DIGITALIA DRAMATICA EDUCATIO ARTIS GYMNAST. ENGINEERING EPHEMERIDES EUROPAEA GEOGRAPHIA GEOLOGIA HISTORIA HISTORIA ARTIUM INFORMATICA IURISPRUDENTIA MATHEMATICA MUSICA NEGOTIA OECONOMICA PHILOLOGIA PHILOSOPHIA PHYSICA POLITICA PSYCHOLOGIA-PAEDAGOGIA SOCIOLOGIA THEOLOGIA CATHOLICA THEOLOGIA CATHOLICA LATIN THEOLOGIA GR.-CATH. VARAD THEOLOGIA ORTHODOXA THEOLOGIA REF. TRANSYLVAN
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STUDIA PHYSICA - Issue no. 2 / 2002 | |||||||
Article: |
SURFACE-ENHANCED RAMAN SPECTROSCOPY OF 5-(4 BROM-PHENYL)-FURAN –2 CARBALDEHIDE ON SILVER SOL. Authors: T. ILIESCU, FLORIN-DAN IRIMIE, M. BOLBOACA, CSABA PAIZS, IOAN BRATU, R. PACURARIU, WOLFGANG KIEFER. |
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Abstract: FT-Raman and SER spectra of 5-(4-brom-phenyl)-furan-2 carbaldehide at pH 1 were recorded and analyzed. The absence of carbonyl band in SER spectrum was explained by the hydration of carbonyl bond. The shift by 5-13 cm-1 of SERS bands and change in their relative intensity by comparing with ordinary Raman spectrum, indicate the chemisorption of the sample molecules on the silver surface via the nonbonding electrons of the ring oxygen. | |||||||