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    STUDIA CHEMIA - Issue no. 4 / 2015  
         
  Article:   SYNTHESIS AND CHARACTERIZATION OF FULLERENE-PYRIDYL ARENE RUTHENIUM COMPLEXES.

Authors:  .
 
       
         
  Abstract:   Association of [60]fullerene with arene ruthenium moieties has been achieved for the first time. Two fullerenopyrrolidine derivatives (Npyr-C60) were synthesized via a 1,3-dipolar cycloaddition, and coordinated to arene ruthenium complexes to form two half-sandwich complexes of the general formula (p-cymene)RuCl2(Npyr-C60). The coordination of the fullerenopyrrolidines to the arene ruthenium unit was evidenced by NMR spectroscopy and mass spectrometry, thus confirming the formation of these novel arene ruthenium complexes. 

Keywords: fullerene; arene ligand; ruthenium; pyridyl ligand; half-sandwich complexes
 
         
     
         
         
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