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Design of a hypothetical crystal network, consisting mostly of pentagon rings and called diamond D₅, is presented. It is shown that the seed and repeat-units, as hydrogenated species, show good stability, compared with that of C₆₀ fullerene, as calculated at three levels of theory (PM3, HF/6-31G(d,p), B3LYP/6-31G). The topology of the network is described in terms of the net parameter.

Keywords: diamond D₅; nano-dendrimer; multi-tori; crystal-like network.