AMBIENTUM BIOETHICA BIOLOGIA CHEMIA DIGITALIA DRAMATICA EDUCATIO ARTIS GYMNAST. ENGINEERING EPHEMERIDES EUROPAEA GEOGRAPHIA GEOLOGIA HISTORIA HISTORIA ARTIUM INFORMATICA IURISPRUDENTIA MATHEMATICA MUSICA NEGOTIA OECONOMICA PHILOLOGIA PHILOSOPHIA PHYSICA POLITICA PSYCHOLOGIA-PAEDAGOGIA SOCIOLOGIA THEOLOGIA CATHOLICA THEOLOGIA CATHOLICA LATIN THEOLOGIA GR.-CATH. VARAD THEOLOGIA ORTHODOXA THEOLOGIA REF. TRANSYLVAN
The STUDIA UNIVERSITATIS BABEŞ-BOLYAI issue article summary
The summary of the selected article appears at the bottom of the page. In order to get back to the contents of the issue this article belongs to you have to access the link from the title. In order to see all the articles of the archive which have as author/co-author one of the authors mentioned below, you have to access the link from the author's name.
Authors: CĂTĂLIN ȘALGĂU, ANDREA DOBRI, ANCA SILVESTRU.
DOI: 10.24193/subbchem.2021.3.10
Published Online: 2021-09-30
Published Print: 2021-09-30
pp. 175-185
VIEW PDF
FULL PDF
The mercury(II) complexes [Hg(SCN)2{PPh[C6H4(CH2NMe2)-2]2}] (1) and [2,6-(Me2NCH2)2C6H3Se][HgCl3] (3) were prepared and structurally characterized in solution by multinuclear NMR and ESI mass spectrometry. The reactions performed to obtain the complex [2,6-(Me2NCH2)2C6H3SeHgCl] (2) failed and we could isolate only a mixture of 3 and [(HgCl2)3{2,6-(Me2NCH2)2C6H3}] (4). Compounds 1 and 4 were characterized by single-crystal X-ray diffraction.
Keywords: mercury(II) complexes, triarylphosphane, organoselenium ligand; intramolecular coordination; solution behavior, solid state structure.
