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    STUDIA CHEMIA - Issue no. 3 / 2010  
         
  Article:   SYNTHESIS, SEPARATION AND X-RAY DIFFRACTOMETRY INVESTIGATIONS OF TRANS, TRANS 1,4-BIS(5’-HYDROXYMETHYL-2’,5’-DIMETHYL-1’,3’-DIOXAN-2’-YL)BENZENE.

Authors:  MONICA CÎRCU, VLAD NISTE, RICHARD ATTILA VARGA, EMESE DÉNES, ELENA BOGDAN, CRINA CISMAŞ, ION GROSU.
 
       
         
  Abstract:  

The isolation of pure trans - trans isomer of 1,4-(2,5,5-trimethyl-5,5-dihydroxymethyl-1,3-dioxan-2-yl)benzene via O-protection, column chromatography then deprotection followed by determination of its structure by solid state X-ray diffractometry are reported.

Keywords: 1,3-dioxanes, X-ray structure, supramolecular C-H-π interactions

 
         
     
         
         
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