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AMBIENTUM BIOETHICA BIOLOGIA CHEMIA DIGITALIA DRAMATICA EDUCATIO ARTIS GYMNAST. ENGINEERING EPHEMERIDES EUROPAEA GEOGRAPHIA GEOLOGIA HISTORIA HISTORIA ARTIUM INFORMATICA IURISPRUDENTIA MATHEMATICA MUSICA NEGOTIA OECONOMICA PHILOLOGIA PHILOSOPHIA PHYSICA POLITICA PSYCHOLOGIA-PAEDAGOGIA SOCIOLOGIA THEOLOGIA CATHOLICA THEOLOGIA CATHOLICA LATIN THEOLOGIA GR.-CATH. VARAD THEOLOGIA ORTHODOXA THEOLOGIA REF. TRANSYLVAN
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The STUDIA UNIVERSITATIS BABEŞ-BOLYAI issue article summary The summary of the selected article appears at the bottom of the page. In order to get back to the contents of the issue this article belongs to you have to access the link from the title. In order to see all the articles of the archive which have as author/co-author one of the authors mentioned below, you have to access the link from the author's name. |
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STUDIA CHEMIA - Issue no. 2 / 2012 | |||||||
Article: |
REACTION OF A HETEROTOPIC P,SAs LIGAND WITH GROUP 10 METAL(II) COMPLEXES: A THEORETICAL STUDY. Authors: LUMINIŢA SILAGHI-DUMITRESCU. |
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Abstract: Density functional calculations have been carried out in order to gain some insight into the electronic structure of 1-Ph₂AsSC₆H₄-2-PPh₂ (1) and to investigate the reactions of 1 with group 10 metal dihalides. The obtained results explain well the experimentally observed behaviour of 1 during the investigated complexation reactions and support the trends observed for the isomerisation of the resulted trinuclear trimeric compounds. Keywords: heterotopic P,SAs ligand, palladium complexes, platinum complexes, structural isomerism, DFT calculations. |
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