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    STUDIA CHEMIA - Issue no. 2 / 2003  
         
  Article:   FIRST EXAMPLE OF SELECTIVE NUCLEOPHILICITY OF 1-AZA-5-HYDROXYMETHYL-3,7-DIOXABICYCLO[3.3.0]OCTANES IN ALKOXIDE FORM.

Authors:  CAMELIA BERGHIAN, CARMEN MAIEREANU, NELLY PLÉ, GÉRARD PLÉ, MIRCEA DARABANTU. 		 
       
         
  Abstract:  A rapid and efficient synthesis consisting in the exploit of the nucleophilicity of 1-aza-3,7-dioxabicyclo[3.3.0]octane-5-yl-methoxy group in alkoxide form against reactive halo compounds and masked imidoyl chlorides (as chlorinated π deficient systems) is described. First reaction conditions depending on the halogen and other leaving groups, together with (regio) selectivity of the substitution are discussed.  
         
     
         
         
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