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    STUDIA PHYSICA - Issue no. SPECIAL%20ISSUE / 2001  
         
  Article:   CU(II) AND NI(II) COMPLEXES WITH 2-HYDRAZINO-4-R THIAZOLE DERIVATIVES.

Authors:  LUMINIŢA OPREAN, ADRIANA COMŞA, L. DAVID, O. CRIŞAN, MIOARA COMAN, MARIA NEAMŢU.
 
       
         
  Abstract:  Four new complexes of Cu(II) and Ni(II) with the ligands L1 (2-N-acetyl-salicyliden-hydrazino-4-clormethyl thiazole) and L2 (2-N-acetyl-salicyliden-hydrazino-4-thiazolyl acetic ester) were synthetized and investigated by IR, ESR and UV-VIS spectroscopy and by magnetic susceptibility measurements. A correlation of these data suggest that the complexes are of the type [ML1(CH3COO)]H2O and [ML2(CH3COO)]. L1 and L2 act as tridentate ligands and the complexes have a distorted tetrahedral (D2d) local symmetry around the Cu(II) and Ni(II) ions.  
         
     
         
         
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