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    STUDIA CHEMIA - Issue no. 4 / 2016  
         
  Article:   4-AMINOPIPERIDINE BASED NEW AMINO-s-TRIAZINES AS POTENTIAL DENDRITIC BUILIDING-BLOCKS .

Authors:  ANA-MARIA ȚICALĂ, DAN PORUMB, CARMEN SĂCĂLIȘ, MIRCEA DARABANTU.
 
       
         
  Abstract:  VIEW PDF: 4-Aminopiperidine Based New Amino-S-Triazines as Potential Dendritic Builiding-Blocks

Starting from commercial 4-aminopiperidine, three new amino-s-triazines, seen as potential dendritic building-blocks, were synthesised by chemoselective SN2-Ar amination of cyanuric chloride. A three steps synthetic sequence, (i) Boc-chemoselective N-protection of 4-aminopiperidine → (ii) amination of cyanuric chloride → (iii) deprotection, yielded a novel potential dendritic central unit, 2,4,6-tris[(piperidin-4-yl)amino]-s-triazine.

Keywords: 4-aminopiperidine, SN2-Ar amination, dendritic cores, melamines

Published Online: 2016-12
 
         
     
         
         
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