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    STUDIA CHEMIA - Issue no. 4 / 2007  
         
  Article:   TOWARDS NEW DOUBLE-BONDED ORGANOPHOSPHORUS DERIVATIVES OF C=P=C=P TYPE.

Authors:  GABRIELA NEMEŞ, RALUCA ŞEPTELEAN, PETRONELA M. PETRAR, LUMINIŢA SILAGHI-DUMITRESCU, IOAN SILAGHI-DUMITRESCU.
 
       
         
  Abstract:   New potential precursors for diphosphaallenes with C=P=C=P skeleton have been synthesized. Compounds 2-4 (bearing a 2,4,6-tri-tert-butylphenyl group bound to phosphorus) are stabilized by the large steric hindrance which prevents the approach of monomers to form dimers or oligomers.  
         
     
         
         
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