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The STUDIA UNIVERSITATIS BABEŞ-BOLYAI issue article summary The summary of the selected article appears at the bottom of the page. In order to get back to the contents of the issue this article belongs to you have to access the link from the title. In order to see all the articles of the archive which have as author/co-author one of the authors mentioned below, you have to access the link from the author's name. |
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STUDIA CHEMIA - Issue no. 1 / 2011 | |||||||
Article: |
ELECTROCHEMICAL BEHAVIOUR OF YBaCo4O7 IN NEUTRAL AQUEOUS SOLUTION. Authors: MIRCEA DAN, NICOLAE VASZILCSIN, ANDREA KELLENBERGER, NARCIS DUTEANU. |
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Abstract: Considering the possibility to use YBaCo4O7 as oxygen sensor in different environments, the study of electrochemical behaviour of this compound was extended for neutral aqueous solution. Cyclic voltammetry and electrochemical impedance spectroscopy have shown that the compound behaviour in neutral solution is different than that in alkaline one. Compound porosity was determined using BET technique and the results are in accordance with thermogravimetric studies carried out in oxygen flow for YBaCo4O7 compound, emphasizing the oxygen intake / release by YBaCo4O7. Correlating all these results, an electrochemical mechanism for YBaCo4O7 oxidation in neutral aqueous solution has been proposed. Keywords: mixed oxides, YBaCo4O7, electrochemical behaviour of YBaCo4O7, cyclic voltammetry, electrochemical impedance spectroscopy, BET technique. |
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