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    STUDIA CHEMIA - Issue no. 1 / 2003  
         
  Article:   CURRENT ASPECTS OF THE POLYOXOMETALATE//METAL OXIDE-BASED CLUSTERS. II. SPECIAL ASPECTS.

Authors:  ADRIAN PATRUT, ADRIAN NICOARǍ, DRAGOŞ MARGINEANU. 		 
       
         
  Abstract:  Current special aspects of the polyoxometalate/metal oxide-based clusters are presented and discussed. Polyoxometalate/metal oxide-based clusters with infinite molecules, generated through an inflationary multiplication of a certain discrete molecule, are described and exemplified. Supramolecular entities that consist of a guest polyoxometalate / metal oxide-based cluster incorporated in the cavity of a larger host polyoxometalate/metal oxide-based cluster are also presented and exemplified. Eventually, a new complex system of 100 water molecules encapsulated in the internal cavity of the [Mo132] giant sphere", having the surface pores closed by organic cations, is presented. The probability that this new system with amazing symmetry could open the way towards a new super-supramolecular chemistry is discussed.  
         
     
         
         
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