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    STUDIA CHEMIA - Issue no. 1 / 2003  
         
  Article:   CURRENT ASPECTS OF THE POLYOXOMETALATE//METAL OXIDE-BASED CLUSTERS. I. GENERAL ASPECTS.

Authors:  ADRIAN PATRUT, ADRIAN NICOARǍ, DRAGOŞ MARGINEANU. 		 
       
         
  Abstract:  Current general aspects of the so-called polyoxometalate/ metal oxide-based clusters are reviewed. Anionic molecules, for which the term polyoxometalate clusters is accurate and similar neutral molecules, for which the term metal oxide-based clusters should be used are discussed. The justification for using the term cluster in the case of polyoxometalate/ metal oxide-based molecules, which contain only metal centres bonded exclusively through bridging oxygen atoms are presented. Two generations of polyoxometalate/metal oxide-based clusters, named clusters of classic type, respectively clusters with supramolecular properties are also described and exemplified.  
         
     
         
         
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